If you have done any research about maintaining a healthy freshwater tank, you have probably read a great deal about pH and its effect on tank inhabitants. Not only does the pH level of your tank affect the water quality, but it can also …
In Part 1 of this two-part article you’ll discover some of the reasons why pH levels can drop in your aquarium and what you can do about it.
If you have done any research about maintaining a healthy freshwater tank, you have probably read a great deal about pH and its effect on tank inhabitants. Not only does the pH level of your tank affect the water quality, but it can also have an impact on the health and vitality of your fish. Many novice aquarium hobbyists experience problems with low pH or a sudden drop in pH in their tanks and, when this happens, they are at a loss what to do. If you are experiencing pH problems in your tank, it is wise to first identify the cause of the problem and to make the necessary corrections before taking steps to adjust the pH back to a normal level.
The Basics about Aquarium pH
The pH of your aquarium is simply a measure of how acidic or alkaline your tank water is and it is measured on a scale from 1 to 14. A pH value of 7.0 is neutral while values below 7.0 are considered acidic and values above 7.0 are considered alkaline. Most species of aquarium fish can tolerate a pH range from 6.5 to 7.5 but certain species like some cichlids are very sensitive to changes in pH and require a certain, stable level. Before you set up your tank for the first time it is wise to test the pH of the tap water you intend to use to fill your tank. The pH of your tap water may vary according to where you live and, depending on the species of fish you plan to keep, you may need to make adjustments to reach the ideal pH level in your tank. Once you have established the proper pH it is a good idea to monitor it with weekly water tests so you can catch any changes in pH before they become a major problem. It is not uncommon for aquariums to suffer a change or drop in pH and the sooner you take action to correct it, the less likely it will be to have a negative effect on your fish.
Causes for a Drop in pH
You already know that low pH values (values below 7.0) are considered acidic, so it makes sense that the pH level in your tank will drop following the addition of acids. Extra acid can make its way into your tank through several means — some are naturally occurring and some may be the result of a mistake on your part. Some of the naturally occurring causes of a pH drop include excess carbon dioxide, tannins from driftwood and the nitrification stage of biological filtration. Carbon dioxide (CO2) is the natural product of respiration, so the more fish you have in your tank the higher your CO2 levels are likely to be. The decay of plant matter can also increase the CO2 levels in a tank and many biofilters actually produce carbon dioxide. The best way to counteract high CO2 levels is to ensure that you have plenty of live plants in your tank – live aquarium plants utilize CO2 in the process of photosynthesis, using light as an energy source to convert CO2 into oxygen for respiration.
Another possible cause for a drop in pH is the leaching of tannins from driftwood or leaf litter. Driftwood is often used for décor in the aquarium trade because it provides cover for fish while enhancing the “natural” appearance of the tank. If you do not properly treat your driftwood before adding it to the tank, however, it can cause problems with your water chemistry. Driftwood contains tannins, or tannic acid, a natural compound occurring that stains water yellow or brown – tannins are responsible for creating “blackwater” habitats like the Amazon River. To prevent tannins from affecting your water chemistry, boil the driftwood or soak it for a period of several weeks before adding it to the tank. Boiling and soaking driftwood will help facilitate the release of the tannins, thus decreasing the chance that the driftwood will cause a pH drop in your tank.
In addition to excess carbon dioxide and tannins in the water, a pH drop may also be caused by the nitrification stage of biological filtration. Nitrification is the process through which beneficial bacteria in the aquarium convert ammonia to nitrite and then into nitrate. Ammonia is a substance toxic to fish, so the process of converting it into nitrate is extremely important for maintaining a healthy tank. During this process, however, your tank may experience a natural drop in pH as a result of the production of nitrite ions. Once your tank has properly cycled, however, it should establish a balance capable of counteracting this drop in pH to keep the water chemistry stable for your tank inhabitants.
Click Here for Part 2 of “What Are The Main Causes Of Low Ph In An Aquarium”
Maintaining stable water chemistry is the key to keeping your freshwater aquarium running smoothly and your tank inhabitants healthy. If the water quality in your tank decreases or your tank experiences a sudden change in water chemistry, your fish could become stressed and may even die. One of the most important aspects of water chemistry is pH and there are a variety of factors which may lead to a change or drop in pH. In addition to naturally occurring conditions such as excess carbon dioxide, tannins from driftwood and the nitrification stage of biological filtration, a drop in pH could also be the result of a mistake on your part as an aquarium hobbyist. Overdosing your tank on medications or adding the wrong kind of substrate can have a negative effect on the pH in your aquarium and, if you do not take quick action to remedy the mistake, your fish could suffer.
When it comes to selecting the substrate for your freshwater tank, you have many options to choose from. Standard gravel and aquarium sand are two of the most popular options, but some aquarium hobbyists are tempted to go a different route for the sake of being unique. Certain aquarium substrates like Oil Dri, Turface and Soilmaster have all been known to cause a drop in aquarium pH. If you plan to use any of these substrates in your aquarium, be aware of this possibility and consider mixing it with another substrate to balance it out. Another substance many aquarium hobbyists use as substrate in their tanks is peat moss — it is typically used as a fertilizer for planted tanks and is often covered with a layer of some other substrate to prevent it from staining the water. Like driftwood, peat moss contains tannins or tannic acids that naturally lower the pH of aquarium water. To avoid having problems with a drop in pH, be aware of the potential side effects of whatever type of aquarium substrate you choose. Standard aquarium gravel and sand are unlikely to have an effect on aquarium water chemistry, so if you are looking for a risk-free option one of these substrates may be your best choice.
If your aquarium experiences a sudden drop in pH it is wise to take quick action to remedy the situation before your fish come to any harm. Luckily, there are several simple ways to increase aquarium pH. One of the easiest ways to raise the pH in your tank is to add baking soda (sodium bicarbonate). Adding 1ml of baking soda per 10 liters of tank water can raise the pH as high as 8.2, so add the baking soda slowly and monitor the pH as you go so you can stop when it reaches the appropriate level. Another way to increase the pH in your tank is to add equal parts baking soda, Epsom salt and marine salt to the tank at a rate of 1ml per 10 liters of tank water. This mixture will not only raise the pH of your tank but it may also increase the water hardness, so exercise caution when utilizing this method to avoid hardening the water in your tank too much. Though this method is not recommended as a means of temporarily raising pH, the addition of calcitic gravel to your tank can also increase the pH. Not only does calcitic gravel increase aquarium pH, but it also increases the buffering capacity of the water so it is unlikely to drop below 7.5. If the fish in your tank require a neutral or slightly acidic pH, do not use this method to correct a drop in pH because it could raise the pH level too high.
If your fish are suffering from ammonia poisoning as a result of excess ammonia in the tank water, the first thing you should do is treat them for this condition. Begin by testing the ammonia levels in your tank water using an aquarium water test kit – if the test results come back with an ammonia level above 1ppm it is essential that you begin treatment immediately. The quickest way to bring relief to fish suffering from ammonia poisoning is to lower the pH of your tank below 7.0. The toxicity of ammonia increases at a higher pH, so lowering the pH in your tank will help mitigate the damaging effects of the ammonia. Performing a 50% water change along with several additional water changes over a period of several days may also help lower the ammonia level in your tank below 1 ppm.
While lowering the pH in your tank and performing a large water change are two of the quickest ways to reduce ammonia levels, there are a variety of things you should do to keep the ammonia in your tank from getting out of control in the first place. Avoid adding too many new fish to your tank at once because such a sudden addition to the biological load of the tank could shock the system – the colonies of beneficial bacteria in your tank need time to adjust to increased levels of waste production in order to keep ammonia and nitrite levels under control. On a related note, it is unwise to feed your fish too much because this too could result in excess waste production and the accumulation of uneaten fish food. Experienced aquarium hobbyists often recommend feeding freshwater fish small quantities of food twice a day. Only offer your fish as much as they can eat in a 3 to 5 minute period of time and remove uneaten portions of sinking wafers and discs after an hour, before they completely dissolve.
There are two different forms ammonia can take in the home aquarium: free ammonia (NH3) or ammonium ions (NH4). The amount of each of these compounds, as well as their level of toxicity, depends on various environmental factors in your tank. The first way ammonia can enter your aquarium is through your tap water. Most tap water has been treated with either chlorine or chloramine to make it safe for human consumption but, as you may be aware, both of these chemicals are toxic to fish. What you may not know is that chloramine is formed by binding chlorine to ammonium. Thus, using tap water that has been treated with chloramine can increase the ammonia content in your tank. While most water conditioners effectively remove chlorine and chloramine from tap water, the ammonium bound to the chlorine atoms may also be released into the water at this time. To prevent this from causing problems in your tank, look for a water conditioner that treats both chlorine and ammonia.
The final way in which ammonia can enter the tank is through your fish. As your aquarium fish eat and digest protein, their bodies absorb the amino acids that serve as the building blocks of those proteins. These amino acids are then distributed throughout the bodies of your fish as needed where they can be synthesized into a new protein to foster healthy growth. Any excess amino acids are returned to the liver where they are broken down, or they may be rejected into the blood and the ammonia left over from these processes is excreted through the gills. If your fish are given more protein than their bodies can effectively use, it could result in the rejection of a large quantity of amino acids and thus the release of high quantities of ammonia into the tank.
Even if you are a novice aquarium hobbyist, you probably know by now that too much ammonia in the aquarium is bad. What you may not know, however, is exactly what kind of problems excess ammonia can actually cause in the home aquarium. The major problem with excess ammonia is that it leads to a decrease in water quality. Maintaining high water quality in your tank is essential for maintaining the health of your aquarium fish – if the water quality in your tank declines, the health of your fish may decline as well. Another problem caused by excess ammonia is ammonia poisoning. Ammonia is a toxic chemical for aquarium fish and it acts as a tissue irritant, targeting exposed tissue like the gills. Excess ammonia can lead to hemorrhaging in the gills along with a condition called hyperplasia which may reduce the ability of fish to absorb oxygen from tank water. Additionally, the damage to the gills caused by ammonia can inhibit the ability of fish to excrete ammonia from the body, thus leading to internal damage as a result of high ammonia levels in the body. Ammonia poisoning is a very serious condition, one which can be fatal to fish, so it is important to monitor the ammonia levels in your tank and to take steps to control excess ammonia.
Fortunately, monitoring the water parameters in your tank is easy – all you need is an
Thankfully, testing the water quality in your aquarium has been made easy by the availability of
Buffering Capacity
Salinity
To keep the water quality in your tank high, and the fish in your tank healthy, you should not only know what water chemistry is, but you should also learn how to manipulate it. It is not enough to understand that pH is simply a measure of how acidic or alkaline the water in your tank is – you need to know how to alter it if it becomes necessary. While pH is one of the most important aspects of water chemistry, it is not the only one. Elements that are also included are water hardness, buffering capacity, salinity and electrolytes. If you have a basic understanding of the principles of water chemistry, and how to alter it, you’ll be better equipped to make changes to your tank when necessary. Quick action on your part can mean the difference between a drop in pH being quickly remedied or killing all the fish in your tank.
Softening Water





